Contemporary Metal Boron Chemistry I

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Borylenes, Boryls, Borane o-Complexes, and Borohydrides

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Borylenes, Boryls, Borane o-Complexes, and Borohydrides

The ?eld of metal boron chemistry has been an especially active one since the 1960s. Much of the early work centered on the synthesis and structural characterization of polyhedral metallaborane and metallacarborane clusters, which will not be discussed in the current Volume. However, early work on metal boryl complexes by Noth et al. also appeared during this period, - thoughthe?rstsimple metalborylcomplexestobestructurallycharacterized bysingle-crystalX-raydiffractionwerenotreporteduntil1990(indeed, crystal structuresofiridiumhydridoborylcomplexeswerereportednearlysimulta- ouslybyBaker, Marder, etal. [1]andbyMerolaetal. [2]), andthisnewinterest in the area arose speci?cally as a result of the report by Noth et al. [3] on the rhodium-catalyzed hydroborationof alkenes using catecholborane. Although there had been previous reports of metal-catalyzed hydroboration employing polyhedralboranesorcarboranesastheB-Hsource[4], theseminal paper by Noth et al. in 1985 [3] marked the beginning of interest by the organic ch- istry community in the application of this reaction in organic synthesis [5]. Whatensuedwasaveryrapidincreaseinthenumberofmetalborylcomplexes to be synthesized and structurally characterized, along with studies of their reactivity, in conjunctionwithan equally rapid growthinthedevelopment of catalytichydroborationchemistry[5]anditsasymmetricversion[5e]. Thiswas followedbyawidevarietyofotherborylationreactionscatalyzedbytransition metals including diborations, silylborations, stannylborations, and thiabo- tions of unsaturated organic substrates [6], borylations of ?, ?-unsaturated carbonyl compounds [7], borylations of C-halide bonds [8], and most - cently, borylations of C-H bonds in alkenes, arenes, heteroarenes, and even alkanes[9,10]. TheC-halideandC-Hborylationchemistryhasbeendrivenby thedevelopment andbroadapplicationoftheSuzuki-Miyaura cross-coupling reaction[11], whichisnowoneofthemainC-Cbond-formingreactionsinthe arsenal of the organic chemist. Thus, the synthetic and structural chemistry ofmetalborylcomplexeshasgrownalongwithcatalyticapplicationsinwhich metal borylcomplexes are key intermediates. Likewise, the importance of metal borane?-complexes as intermediates in many catalytic reactions has only recently been recognized [12], and thisarea is now a rapidly expanding one.

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اشاعه ی کودک آزاری
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بستن

فرمت کتاب

ebook

زبان

english

تاریخ انتشار

2008

نویسنده

Zhenyang Lin

ناشر

Springer

شابک

9783540786337

20,000 تومان

خرید کتاب مطالعه نمونه درخواست ترجمه کتاب

خرید کتاب Contemporary Metal Boron Chemistry I

Contemporary Metal Boron Chemistry I

گزارش تخلف

فرمت کتاب

ebook

زبان

english

تاریخ انتشار

2008

نویسنده

ناشر

شابک

کتاب های مرتبط

Contemporary Metal Boron Chemistry I

Organoboranes for syntheses

Physics and chemistry of metal cluster compounds : model systems for small metal particles

Reactivity of metal-metal bonds : based on a symposium sponsored by the Division of Inorganic Chemistry at the second chemical congress of the North American Continent (180th ACS national meeting) Las Vegas, Nevada, August 25-26, 1980

Solvent Effects and Chemical Reactivity

Electron, Spin and Momentum Densities and Chemical Reactivity

Electron, Spin and Momentum Densities and Chemical Reactivity

Liaisons chimiques : structure et réactivité

NMR Studies of Translational Motion

Electron, spin and momentum densities and chemical reactivity

Reaction Mechanisms in Sulphuric Acid and Other Strong Acid Solutions

Activation of Unreactive Bonds and Organic Synthesis

Electronic Structure of Organic Compounds

Liaisons chimiques : structure et réactivité

Organic chemistry : reactions

Diffusion And Reactivity Of Solids

The Properties of Energetic Materials

Reaktsionnaia Sposobnost' Tverdykh Veshchestv

Reactive Distillation Design and Control

Selective fluorination in organic and bioorganic chemistry

NMR Studies of Translational Motion

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